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It does not appear to be corrosion/wear.Is that corrosion ?
I've read in a few places, a long time ago, where people would use various metals turned down for bullets and would put bluing on the shoulder areas to keep down galvanic* response between it and the brass. Dunno. Maybe.
*--A galvanic reaction occurs when two dissimilar metals are in electrical/acidic/humid contact with one another which causes one metal to corrode. Noble metals (gold, silver, platinum, palladium) are resistant to corrosion and oxidation. When these metals are mated with more corrosive metals (tin), a Galvanic reaction would occur.